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16) The PCs find a Great Wyrm Sleeping in the middle of the road. Those who are brave enough to venture forward find it smell heavily of alcohol. The PCs have, indeed, discovered a drunk dragon. Once a minute it burps its breath weapon - roll reflex.

18) The players are in a spooky ancient cathedral to forgotten gods. A giant evil piggy breaks down the front wall. Roll initiative.

20) Your PCs have been happily enjoying some relaxation at the tavern after some successful adventuring. It starts to rain ... and doesn't stop. Save the village ... from a flood! (now thats a little unusual).

22. PC Villain is in love with an imprisoned NPC Villain, and wants to free her.

23. Villain is in love with a Hero, and knows that they can never truly be together. So the Villain keeps on fighting the Hero so that they can at least in this perverse way be together. Alternatively, the Villain tries to make sure that no one else can love the Hero.

24. In order to die, the Villain must kill 100 sinners. The Villain cannot rest until this is completed, and lives in torment until that day. See "Blade of the Immortal" comic books.

25. Villain is obsessed with becoming stronger, and constantly fights/challenges heroes.

26. Villain(?) sees future, and preemptively kills or disables people who are likely to kill in the future. See "Minority Report" movie.

27. Villain believes he is the rightful ruler of (somewhere). Perhaps his claim is legit, perhaps not. But he starts a military campaign of conquest.

28. Villain(?) is tormented by [individual X, government organization Y], so the villain goes on an expansive quest of vengeance.

29. Villain(s) is accused of a crime, and accidentally commits crimes while trying to prove they're not guilty of the previous crime! So...they're in a big mess, and they have enough rationale to say it's not their fault...And they don't have to necessarily blame themselves for the crimes that they were "forced" to commit...

30. The Heartstone
A young girl kidnapped has managed to escape into the hands of the heroes. Villains took her as they believe she is the key to finding the Heartstone - a stone that will bring love to it's owner. The villains think they can use it to gain control over the emotions of love. Unbeknownst to everyone, the stone is the girl's actual heart - she is lacking an organic heart. As a second twist, there is a second batch of thugs out to get the stone because their hapless and misguided [but not really evil] leader desires true love. This group also knows the girl has some connection, but not the true nature of that connection nor the fact that the girl is actually their leader's lost daughter [and thus the true love he/she actually seeks].
Potential Scenes:
Scene one: Girl finds heroes just as villains catch up to her.
Scene two: At a place the Heartstone was rumored to be, a three way battle to get the girl [who was the only one able to open some seal to grant entry to this place].
Scene Three: Heroes must team up with one villain group to get the girl back from the other. If this was the wrong alliance to make [bad villains] betrayal will occur at some point.