It can only target spells that target players. While the card of Triumph of Cruelty is an enchantment spell on the stack, its ability is a triggered ability, not a spell. Only sorcery, instant and enchant player auras will target a player while they are spells on the stack.
Sorry if I'm not explaining that well. A spell is (generally) the physical card that you play, while an ability is (generally) something that triggers or activates from a permanent.
A spell is a card (or a copy) on the stack. If it doesn't target a player while it is a spell, it can't be countered by Outwit.
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