Another Dark Temptation

Can you use Dark Temptation on an Attack of Opportunity, or extra attack granted by a CE?

If so, does it last until the end of your next turn?

Conversely, if it only lasts the current turn, do you have to make a save at the end of the current turn?
RS 55/60; CS 54/60; RotS 55/60; UH 46/60; CotF 60/60; BH 44/60; A&E 58/60; FU 49/60; LotF 60/60; KotOR 57/60;
CW 40/40; IE 39/40; JA 40/40; GaW 40/40; DT 39/40; MotF 40/40
Sorry, just found this on the Rules Insert
RS 55/60; CS 54/60; RotS 55/60; UH 46/60; CotF 60/60; BH 44/60; A&E 58/60; FU 49/60; LotF 60/60; KotOR 57/60;
CW 40/40; IE 39/40; JA 40/40; GaW 40/40; DT 39/40; MotF 40/40